Congratulations to Alta and Mikko who have recently published their study on nanowire growth in the Journal of the Electrochemical Society. Fabricating nanowires through a porous template via electrodeposition in a controlled manner is not an easy task given the complex physics and geometries involved in the problem. In particular, the nanowires tend to grow in a nonuniform manner, and the physical explanation for the nonuniformity is not clear. In this study, the authors perform a thorough investigation into the possible causes that include irregularities in nucleation times, pore lengths, cracks, branching, etc. They employ the phase-field method and statistical techniques to identify growth rate as the likely culprit. Read the paper to learn more.
Over the past year, Ryan and Mikko have been conducting an investigation into the stability of multiphase catalyst structures. These systems, known as supported-metal catalysts, are fabricated through a method called infiltration and are used in applications such as solid-oxide fuel cells. While these structures initially exhibit favorable features at a nanometer length scale, this study identifies the thermally activated mechanisms that cause catalyst deactivation. The work was recently published in the Journal of Power Sources, and you can read more about the findings here.
Congratulations to our esteemed colleague, Alta Fang, who has successfully defended her research on solidification and deposition. Her thesis, titled “Modeling Microstructural Evolution During Crystallization From Organic Thin Film To Electrodeposited Metals,” will soon be available on Princeton’s database for public access. Alta recently accepted a post-doctoral fellowship at NIST in Boulder, Colorado. Working with Alta has been a pleasure and a privilege, and we wish her luck in her future endeavors.
A paper by our group, in collaboration with David Srolovitz’s group at UPenn, was recently published in Nano Letters [view pdf or view at publisher]. A multiscale modeling framework was formulated to describe structural transformations in transition metal dichalcogenide (TMD) monolayers. It was demonstrated that application of strain can be used to control the morphology and mechanical response of these elastically bendable 2D materials in order to generate functionally patterned domains of the metallic/semimetallic T’ phase. This enables dynamically programmable 2D materials with locally conducting regions that can be “drawn” in real time.
A paper by Mikko was recently published in Biophysical Journal [view pdf or view at publisher]. It is shown that fluctuation-induced interactions of compositional domains in multicomponent lipid bilayer membranes provide a means for co-localization of domains in the two leaflets. Spatial variations in membrane bending rigidity are demonstrated to lead to an attractive interleaflet coupling that is robust against membrane tension and
Research from our group, in collaboration with the groups of Jared Toettcher and Cliff Brangwynne, was recently published in a Cell paper [view pdf or view at publisher]. Light-dependent triggering of protein association allows selective temporal and spatial control of droplet and gel formation aimed at understanding the different forms of membrane-less bodies and fibrillar structures within cells. More information can also be found in this Princeton news article.
Ryan presented a poster titled “Simulating Fracture in SOFC Anode Materials” at the Fifth Annual Princeton E-ffiliates Partnership Meeting. His poster features a phase-field model of brittle fracture that captures the stresses induced from oxidation in fuel cells and the resulting fracture events. Check out the poster!
A simulation study of twisted crystal growth in organic thin films has recently been published in Physical Review E [view pdf or view at publisher]. We developed a phase-field model that energetically favors twisting of the 3D crystalline orientation about and along particular axes, allowing us to simulate a variety of morphologies, including banded spherulites, curved dendrites, and “s”-shaped or “c”-shaped needle crystals. In curved dendrites, we find that the twisting rate affects not only the morphology but also the kinetics of crystallization.
Our investigation of the assembly dynamics of membraneless biological organelles was published this week in the online Early Edition of Proceedings of the National Academy of Sciences [view pdf or view at publisher]. In collaboration with Stephanie Weber, Nilesh Vaidya, and Cliff Brangwynne from the Department of Chemical and Biological Engineering, we have shown that the assembly dynamics of liquid-phase nuclear bodies (condensed droplets rich in RNA and protein) in C. Elegans embryos can be explained by classical models of phase separation and coarsening long associated with nonliving condensed matter – namely Brownian coalescence and, to a lesser degree, Ostwald ripening. Our findings also indicate that highly nonequilibrium biological activity such as rRNA transcription, rather than fundamentally altering the passive phase separation mechanisms, can act to locally modulate the thermodynamic parameters governing phase separation, thus locally fine tuning organelle size and stability in response to developmental or environmental conditions.